Synthesis of polyHIPEs through high internal phase emulsions of β-myrcene

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dc.contributor.authorMert, Emine Hilal, Burcu Kekevi
dc.date.accessioned2022-03-09T07:20:38Z
dc.date.available2022-03-09T07:20:38Z
dc.date.issued2020-08-20
dc.description.abstractPolyHIPEs are an important class of porous polymers with well-defined hierarchical porosity and tunable morphology. However, the insufficient mechanical properties arise due to high volume of voids bringing difficulties in applications. In this study, polyHIPEs with tailored morphological and mechanical properties were prepared by using a monoterpene for the first time. In this respect, copolymerization of β-myrcene with several comonomers within water-in-oil (w/o) high internal phase emulsions (HIPEs) has been extensively investigated. Accordingly, combining β-myrcene and ethylene glycol dimethacrylate (EGDMA) in polyHIPE structure was demonstrated as a successful approach for tailoring the morphology, as well as the mechanical strength. PolyHIPEs with cavities between 1.09 and 3.55 μm were obtained by changing the ratio of β-myrcene in the continuous phase of HIPEs. Moreover, resulting polyHIPEs have found to have improved mechanical strength. The highest compressive modulus achieved for the obtained monoliths was determined to be 38.8 MPatr_TR
dc.description.sponsorshipno fundingtr_TR
dc.identifier.citationSCİ-EXPtr_TR
dc.identifier.urihttp://dspace.yalova.edu.tr/handle/1/513
dc.language.isoentr_TR
dc.publishercolloid and polymer sciencetr_TR
dc.relation.ispartofseries298;1423–1432
dc.subjectPolyHIPE . High internal phase emulsion . β-Myrcene . Morphology . Mechanical propertiestr_TR
dc.titleSynthesis of polyHIPEs through high internal phase emulsions of β-myrcenetr_TR
dc.typeArticletr_TR
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