Synthesis of multiarm star block copolymer based on host-guest inclusion complexation
dc.contributor.author | Çakır Yiğit, Neşe | |
dc.contributor.author | Hızal, Gürkan | |
dc.contributor.author | Tunca, Ümit | |
dc.date.accessioned | 2022-03-03T16:57:12Z | |
dc.date.available | 2022-03-03T16:57:12Z | |
dc.date.issued | 2022-01 | |
dc.description.abstract | Supramolecular multiarm star block copolymer ((CD-PEG)p-(Ada-PS)n-polyDVB) was prepared by hostguest interaction of -cyclodextrin ( β-CD) end functionalized polyethylene glycol (β-CD-PEG) and adamantane peripherally functionalized multiarm star polymer ((Ada-PS)n-polyDVB). The β-CD-PEG was synthesized by copper-catalyzed azide/alkyne cycloaddition reaction (CuAAC) of alkyne functional PEG with mono azide functional β-CD (β-CD-N3). Adamantane functional polystyrene (Ada-PS) was prepared by atom transfer radical polymerization (ATRP) of styrene (St) and was allowed to react with divinyl benzene (DVB) as a linking agent giving (Ada-PS)n-polyDVB multiarm star polymer. The structures of β-CD-PEG and (Ada-PS)n-polyDVB multiarm star formation were determined by 1H NMR and GPC. 2D ROESY NMR and DLS analysis of (CD-PEG)p-(Ada-PS)n-polyDVB were carried out to validate the formation of the inclusion complex. The evidence of increased molecular weights and size distributions supported the supramolecular multiarm star block copolymer formation. | tr_TR |
dc.identifier.uri | http://dspace.yalova.edu.tr/handle/1/285 | |
dc.language.iso | en | tr_TR |
dc.subject | Star Polymer | tr_TR |
dc.subject | ATRP | tr_TR |
dc.subject | CuAAC click | tr_TR |
dc.subject | Host-guest interaction | tr_TR |
dc.title | Synthesis of multiarm star block copolymer based on host-guest inclusion complexation | tr_TR |
dc.type | Working Paper | tr_TR |
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